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Модуль электромагнитной левитации Эта простая инженерная система управления использует регулируемый электромагнит (медная катушка) и датчик магнитного поля Холла (встроенный в центр катушки) для левитации неодимового магнита и предотвращения его падения. #интереснаяфизика

https://t.me/chemistrytg2021/9571?embed=1&mode=tme

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https://t.me/s/chemistrytg2021

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[{"ner":"Холла","lemma":"холл","label":"PER","start_pos":156,"end_pos":161}]

NEUTRAL

rus

NOT SPAM

Фотография анодированного титана. ⠀ Анодирование (анодное окисление) — процесс создания оксидной плёнки на поверхности некоторых металлов путём их поляризации в проводящей среде.

https://t.me/chemistrytg2021/9572?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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NEUTRAL

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На сайте Научной электронной библиотеки Elibrary.ru опубликован очередной номер Журнала аналитической химии (том 79, № 5, 2024 г.) Содержание номера со ссылками на статьи: Обзоры Использование двумерной корреляционной спектроскопии в химическом анализе. Муратова М.Е., Михеев И.В., Волков Д.С., Проскурнин М.А. Индексы экологичности в аналитической химии. Шишов А.Ю., Моходоева О.Б. Оценка содержания микропластика в природных водах и донных отложениях: пробоотбор и пробоподготовка. Ермолин М.С. Оригинальные статьи Новые супрамолекулярные структуры на основе наночастиц серебра и мицеллоподобных агрегатов из цетилтриметиламмония бромида. Романовская Г.И., Королева М.В. Определение изониазида фотометрическим методом за счет ковалентного связывания с карбоцианиновым красителем. Скоробогатов Е.В., Тимченко Ю.В., Дорошенко И.А., Подругина Т.А., Родин И.А., Беклемишев М.К. Осаждение и флотационное концентрирование ионов неодима, эрбия и тулия алкилбензолсульфокислотой. Заболотных С.А., Денисова С.А., Кочнева Я.К., Райзер А.Е. Флотационное извлечение ионов меди и цинка с N-нонаноил-N'-метансульфонилгидразином. Ваулина В.Н., Чеканова Л.Г., Мулюкова А.Б., Харитонова А.В. Концентрирование стронция и бария соосаждением с органическими коллекторами и их рентгенофлуоресцентное определение. Кузнецов В.В., Прокопенко Ю.Р. Сорбционно-атомно-абсорбционное определение ионов Cu(II) в техногенных водах. Рузметов У.У., Жумаева Э.Ш., Сманова З.А. Выбор внутренних стандартов для определения редкоземельных элементов методом атомно-эмиссионной спектрометрии с микроволновой плазмой. Ким П.В., Полякова Е.В., Николаев Р.Е. Мембранная хроматографическая тест-система для определения бисфенола а в питьевой воде, основанная на использовании аптамера. Комова Н.С., Серебренникова К.В., Берлина А.Н., Жердев А.В., Дзантиев Б.Б. Критика и библиография Введение в хемометрику. Интернет-издание, 2023. 372 С. С. В. Кучерявский, В. В. Панчук, Ю. Б. Монахова, Д. О. Кирсанов. Колотов В.П. Хроника Юбилей Никиты Борисовича Зорова. Юбилей Сергея Александровича Еремина. Юбилей Ефима Соломоновича Бродского. #российскаянаука

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🎯 Что такое рицин и зачем его бояться? 🔬 Рицин — это токсичный белок, который содержится в семенах клещевины. Одно семечко этого растения способно вызвать серьёзное отравление, а в больших дозах — даже смертельный исход. ⚗️ Как он работает? Попав в организм, рицин блокирует выработку белков на клеточном уровне, буквально выключая жизненно важные процессы. А вот вам химический факт: всего 1–2 миллиграмма рицина способны убить взрослого человека, если вещество ввести инъекционно или вдохнуть. 🌱 Где растёт клещевина? В России её можно встретить в южных регионах, таких как Краснодарский край, Ростовская область, Крым и Кавказ. Её культивируют как декоративное растение — выглядит эффектно, а заодно добавляет адреналина садоводам! ⚠️ Серьёзная угроза: Рицин фигурировал в ряде громких криминальных и шпионских дел. С его помощью отправляли политиков и журналистов на тот свет. Но для случайного отравления потребуется неплохая доза в виде семян, так что, если не планируете жевать клещевину, вы в безопасности. 💡 Теперь вы знаете, что за этим красивым растением скрывается опасный секрет. 🌟

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https://t.me/s/incredible_chemistry

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NEUTRAL

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ГЛИКОГЕН. Печень и мышцы, есть ли разница? Продолжая тему гликогена, давайте ответим на вопрос, есть ли разница в дальнейшей судьбе гликогена в печени и в скелетной мускулатуре? 🤔 В комментариях под предыдущим постом многие ответили совершенно верно, разница есть и она значительная! ❗️ Гликоген печени - источник свободной глюкозы в плазме крови! Печень целиком и полностью накапливает гликоген, чтобы далее отдать его органам и тканям в период голода. Особенно нервной ткани! ❗️ Гликоген мышц - источник энергии только для самих себя . Мышцы не отдают свободную глюкозу в кровь! Мускулатура, как ткань с высокими энергетическими потребностями, запасает гликоген только для самой себя. Как вы считаете, обоснован ли такой механизм? 😉

https://t.me/simplebestbiochemistry/565?embed=1&mode=tme

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https://t.me/s/simplebestbiochemistry

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[{"ner":"ГЛИКОГЕН","lemma":"гликоген","label":"ORG","start_pos":0,"end_pos":8}]

NEUTRAL

rus

NOT SPAM

Какую соль выбрать? 🧂 Соль — самая распространённая пищевая добавка, без которой не обходится ни одно блюдо в ресторане или на кухне 🥗 При этом, химический состав её предельно прост и знаком каждому. Откуда тогда на полках в магазине берётся такое разнообразие хлорида натрия? И почему стоимость одной упаковки может быть в десять раз больше, чем другой? Начнём с того, как добывают пищевую соль . ГОСТ выделяет четыре способа производства , которые указывают на упаковке: Каменная соль добывается в шахтах или карьерах из соляных залежей, не подвергаясь тепловой и водной обработке ⛏ Выварочную соль выпаривают из соляных растворов. Бывает так, что строить целую шахту для добычи соли невыгодно. Тогда бурят небольшие скважины, заливают их водой, которая растворяет соль, затем рассол выкачивают, фильтруют и вываривают 💨 Встречаются также естественные подземные рассолы, с которыми поступают аналогичным образом. Садочную соль осаждают из соленой воды в специальных бассейнах. В теплый сезон в местностях с подходящим климатом вода испаряется из искусственных плоских водоёмов, оставляя следы соли 🏝 И, наконец, самосадочная соль — это та, которая оседает естественным образом на дне водоема. Чаще всего это озерная соль. На самом известном в России соляном озере — Баскунчак — получают до 80 % от общей добычи соли в стране 🗻 Согласно одному из основных законов химии — закону постоянства состава — определенное химически чистое соединение, независимо от способа получения , состоит из одних и тех же химических элементов. Вне зависимости от того, как был получен хлорид натрия , он будет иметь однозначную формулу NaCl и обладать одинаковыми химическими свойствами 👁 Другая сторона вопроса — сорт соли , который определяет внешний вид, цвет, вкус, запах и состав продукта. ГОСТ выделяет четыре сорта , для каждого из которых указано минимальное содержание содержание чистого хлорида натрия: экстра — 99,7% , высший — 98,4% , первый — 97,7% , второй — 97% . Остальные проценты — это следование содержания других минералов , характерных для места добычи соли (кальций, магний, калий, железо и т.д.). Эти элементы необходимы для нормальной работы нашего организма, правда получаем мы их в основном из другой пищи 🍎 Как можно заметить, соль ЭКСТРА — это практически химически чистый реактив, подходящий для экспериментов в лаборатории 🧪 А соль первого и второго сорта может иметь тёмные вкрапления соединений железа и других минералов, которые никак не сказываются на её вкусовых качествах. И другая характеристика соли — это помол . Занятно, что при использовании крупной соли блюдо сложнее пересолить , потому что в щепотке крупного помола хлорида натрия на самом деле меньше, чем в щепотке мелкого из-за наличия пустот между кристалликами 💎 Вывод . Как бы ни старался современный маркетинг , вкус дорогой морской соли ничем не будет отличаться от дешёвой каменной. Чем ниже сорт, тем больше содержание других полезных элементов , а чем крупнее помол, тем лучше соль ведёт себя при готовке . И не стоит бояться тёмных частиц — это лишь вкрапления других минералов . Но обращайте внимание на состав 😉 Иногда в соль добавляют компоненты против слёживания и комкования . Если вы желаете купить натуральный продукт , выбирайте упаковку с наиболее кратким и лаконичным составом 👩🏻‍🔬

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https://t.me/s/ychemistry

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NEUTRAL

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На видео пересыщенный раствор ацетата натрия Добавили кристаллик ацетата натрия, чтобы спровоцировать кристаллизацию.

https://t.me/chemistrytg2021/9566?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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NEUTRAL

rus

NOT SPAM

Реакция йодида калия с серной кислотой

https://t.me/chemistrytg2021/9567?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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NEUTRAL

rus

NOT SPAM

Жидкий метан Это криогенная жидкость, которая легко воспламеняется, причем разница температур между пламенем и жидким метаном прямо под ним составляет более 1600C градусов!

https://t.me/chemistrytg2021/9568?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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[{"ner":"1600","lemma":"1600","label":"NUM","start_pos":157,"end_pos":161}]

NEUTRAL

rus

NOT SPAM

Подборка интересных физико-химических экспериментов, которые можно повторить в домашних условиях.

https://t.me/chemistrytg2021/9569?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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NEUTRAL

rus

NOT SPAM

Эксперимент — «Роза в жидком азоте»

https://t.me/chemistrytg2021/9570?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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NEUTRAL

rus

NOT SPAM

Новые мультитаргетные конъюгаты для терапии болезни Альцгеймера Международный коллектив ученых из Института физиологически активных соединений Федерального исследовательского центра проблем химической физики и медицинской химии РАН, Института органического синтеза им. И.Я. Постовского УрО РАН, Института биохимической физики имени Н.М. Эмануэля РАН, Института Вейцмана (Израиль, Реховот), Московского государственного университета им. М.В. Ломоносова, Мичиганского университета (США, Анн-Арбор) разработал новые конъюгаты на основе ингибитора холинэстераз амиридина и салициловых производных (салициламида, салицилимина и салициламина) с алкиленовыми спейсерами различной длины. Соединения продемонстрировали высокую ингибирующую активность в отношении ацетилхолинэстеразы (АХЭ) и бутирилхолинэстеразы (БХЭ), до 3–16 раз превосходя исходный амиридин. Салициламиды со спейсерами (CH2)₆ и (CH2)₈ имели максимальные коэффициенты селективности к БХЭ. Выявлено, что конъюгаты являются обратимыми ингибиторами смешанного типа обеих холинэстераз и вытесяют пропидий из периферического анионного сайта АХЭ на уровне донепезила. Соединения проявили способность ингибировать самоагрегацию Aβ42, которая возрастала с удлинением спейсера. Полученные сведения хорошо согласуются с молекулярным докингом лигандов в АХЭ, БХЭ и Aβ42. Также было показано, что соединения демонстрируют высокую радикал-связывающую активность в ABTS-тесте (сопоставимую со стандартным антиоксидантом тролоксом) и обладают способностью связывать ионы некоторых биогенных металлов - Cu (II), Fe (II) и Zn (II). Кроме того, конъюгаты имеют благоприятную прогнозируемую кишечную абсорбцию и проницаемость гематоэнцефалического барьера. Результаты работы опубликованы в журнале «Archiv der Pharmazie» и могут быть использованы для разработки новых многофункциональных препаратов против болезни Альцгеймера. G.F. Makhaeva, M.V. Grishchenko, N.V. Kovaleva, N.P. Boltneva, E.V. Rudakova, T.Y. Astakhova, E.N. Timokhina, P.G. Pronkin, S.V. Lushchekina, O.G. Khudina, E.F. Zhilina, E.V. Shchegolkov, M.A. Lapshina, E.S. Dubrovskaya, E.V. Radchenko, V.A. Palyulin, Y.V. Burgart, V.I. Saloutin, V.N. Charushin, R.J. Richardson. Conjugates of amiridine and salicylic derivatives aspromising multifunctional CNS agents for potentialtreatment of Alzheimer's disease. Arch. Pharm. 2025;358: e2400819. https://doi.org/10.1002/ardp.202400819 Источник: ИОС УрО РАН #российскаянаука #науказарубежом

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https://t.me/

https://t.me/s/chemrussia

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NEUTRAL

rus

SPAM

Международный научно-технический симпозиум «Повышение энергоресурсоэффективности, экологической и технологической безопасности процессов, аппаратов и производств химической и смежных отраслей промышленности», посвященный 110-летию со дня рождения Л.А. Костандова С 26 по 27 ноября 2025 г. в Российском государственном университете им. А.Н. Косыгина пройдет Международный научно-технический симпозиум «Повышение энергоресурсоэффективности, экологической и технологической безопасности процессов, аппаратов и производств химической и смежных отраслей промышленности», посвященный 110-летию со дня рождения Л.А. Костандова, Мероприятие состоится в рамках V Международного Косыгинского форума «Современные задачи инженерных наук». Симпозиум включает пленарные сессии, работу секций с устным и стендовым представлением докладов. Основные направления работы симпозиума: 1) Теория и математическое моделирование, цифровые технологии в энергоресурсоэффективных процессах и технологических системах. 2) Технология и аппаратурное оформление энергоресурсоэффективных экологически и технологически безопасных процессов, аппаратов и производств химической, нефтегазоперерабатывающей, текстильной, лёгкой, пищевой, деревообрабатывающей, микробиологической, фармацевтической, целлюлозно-бумажной и других отраслей промышленности и АПК. 3) Процессы и системы защиты техносферы (производственная, экологическая и технологическая безопасность, управление рисками). 4) Современные экологически чистые инновационные технологии получения новых функциональных полимерных волокнистых и наноматериалов. Ключевые даты: 15.03.2025 - последний срок регистрации и подачи материалов; до 01.06.2025 – извещение о результатах рассмотрения материалов. Рабочие языки Симпозиума – английский и русский. К началу Симпозиума будут изданы индексируемые в РИНЦ научные труды со статьями на языке оригинала. Каждой из статей сборника научных трудов будет присвоен идентификатор DOI. Отобранные по результатам Симпозиума статьи будут опубликованы в специальных выпусках журналов, входящих в перечень ВАК (Химические волокна, Промышленные процессы и технологии и др.). Во время Симпозиума будет организован Международный конкурс научных работ молодых участников (до 36 лет) «Цифровые решения в инженерных задачах». Конкурс нацелен на мотивацию студентов к профессиональному развитию и освоению современных цифровых технологий проектирования на базе отечественного программного обеспечения, а также формирования навыков необходимых для повышения конкурентоспособности предприятий химической и смежных отраслей промышленности. Подробная информация о мероприятии опубликована на сайте Симпозиума #конференция

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rus

SPAM

ГЛИКОГЕН. Запас на голодные времена Итак, продолжаем разговор про углеводы! Наш организм чрезвычайно умная биохимическая машина. Прекрасно понимая, что часть нашей жизни мы проводим в поисках пищи и состоянии голода, эволюционно организм научился накапливать запас энергии. Как я люблю говорить, «на голодные времена, когда прийдется охотиться на очередного мамонта» 🦣 . Существуют разные биохимические механизмы депонирования энергии, но первый из них - это запас энергии в виде гликогена . ❗️ Гликоген - это длинная углеводная молекула, гомополисахарид, состоящая из большого числа молекул глюкозы, соединенных между собой. Выполняет функцию депонирования глюкозы. Мы выделяем два органа накапливающие гликоген в наибольшем количестве: 1️⃣ Печень (в цитоплазме гепатоцитов); 2️⃣ Скелетная мускулатура; Накапливается гликоген после приема пищи (адсорбтивный период), особенно высокоуглеводистой, под действием гормона инсулина. А вот распадается гликоген обратно до чистой глюкозы в период голода (постадсорбтивный период) под действием гормона глюкагона и адреналина. На фото ⤴️ приведена структура молекулы гликогена. В центре белок - «гликогенин» на который накручиваются сами гликогеновые нити, состоящие из тысяч остатков глюкозы, соединенных между собой. ❓ А теперь важный вопрос, есть ли разница в судьбе гликогена в печени и скелетной мускулатуре? Оба ли они пойдут в кровь в виде чистой глюкозы или есть какие-то различия? Жду ваши варианты в комментариях ⤵️

https://t.me/simplebestbiochemistry/564?embed=1&mode=tme

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[{"ner":"ГЛИКОГЕН","lemma":"гликоген","label":"ORG","start_pos":0,"end_pos":8},{"ner":"1","lemma":"1","label":"NUM","start_pos":738,"end_pos":739},{"ner":"2","lemma":"2","label":"NUM","start_pos":777,"end_pos":778}]

NEUTRAL

rus

NOT SPAM

Почему нельзя выбрасывать батарейки в мусорку? Наверняка вы слышали о том, что батарейки ни в коем случае нельзя выбрасывать в обычную мусорку и уж тем более на улицу. Говорят об этом не ради красного словца. В любой батарейке содержаться такие элементы, как свинец, никель, кадмий, литий и ртуть. Самыми опасными для жизни человека является ртуть и кадмий. Второй элемент очень токсичен. Кадмий негативно влияет на работу почечной системы, костных тканей и печени. Большинство людей считают, что ничего страшного не произойдёт, если они выбросят 1-2 батарейки. Действительно, уровень угрозы будет минимальный. Но что если кроме вас так же подумает ещё 10000 людей? Согласно Гринпис, на свалках одной Москвы было обнаружено около 15 миллионов батареек, а радиус загрязнения окружающей среды равен одному квадратному метру на каждую. Не маленькая цифра, правда? Итак, чем же грозит выброс батареек в мусорку? Батарейки или аккумуляторы в процессе коррозии начинают разрушаться и все токсичные вещества проникают прямиком в почву и грунтовые воды. Если батарейки сжечь 🔥 вместе с прочим мусором, то токсины добираются до атмосферы. Что происходит дальше — очевидно. Распространившись в почве, водоёмах и воздухе, токсичные вещества наносят серьёзный ущерб всему живому на планете. Они замедляют рост растений, попадают в организмы животных и, конечно, человека — вместе с водой, пищей животного и растительного происхождения и даже из вдыхаемого нами воздуха. Это всё может привести к раку и прочим болезням. Помни, забота о планете начинается с тебя, начни прямо сейчас 🌍

https://t.me/ychemistry/1057?embed=1&mode=tme

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NEUTRAL

rus

NOT SPAM

Почему от лимона чай светлеет? Все любители чая, скорей всего замечали, как меняется цвет любимого напитка при добавлении дольки лимона. Но задумывались ли вы почему это происходит? На самом деле всё довольно просто. В любом чае 🍵 содержатся пигменты теарубигины, которые и отвечают за цвет напитка. Они являются кислотно-основными индикаторами среды, и их окраска зависит от кислотности (рН) раствора При добавлении лимона 🍋 или лимонной кислоты понижается рН, ионов водорода в растворе становится больше. Из-за этого структура молекулы незначительно изменяется и цвет становится светлее. Кстати чай 🍵 можно не только осветлить, но и сделать более насыщенным ☕️ и ярким. Для этого потребуется обычная пищевая сода. При понижении кислотности химическое равновесие смещается в другую сторону и цвет напитка становится насыщеннее. Ходят слухи, что раньше, когда не был распространен пакетированный чай, этим любили пользоваться проводники в поездах, воровавшие заварку. Кстати, на крепость чая сода не влияет. Мы привыкли, что тёмный, насыщенный цвет заварки говорит об её терпкости и крепости, но ни в этом случае. Простейшую, но от этого не менее интересную химию можно легко наблюдать на кухне. Даже в обычной, вроде бы, кружке чая с лимоном.

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NEUTRAL

rus

NOT SPAM

Химия конфет Я уже как-то раз писала про карамель, но в этот раз хочу углубиться в химический состав любых конфет. Если честно, я много раз пыталась не есть конфеты и вообще сладости, но все мои попытки заканчивались провалом. Максимум сколько я не ела сладкое было три месяца. Это интересный опыт, рекомендую всем попробовать не есть хотя бы месяц сладкое. 🍭 Не многие знают, но слово «конфеты» и сам продукт произошли от аптекарей XVI века. Да, да именно они придумали лечить анемию засахаренными фруктами. Лекарство получилось настолько вкусным, что его стали употреблять здоровые люди. ⠀ 🍫 Расцвет кондитерской промышленности начался после соединения двух ингредиентов, которые раньше никак не сочетались в природе: жиров и сахара. Большинство всех конфет состоит из сахарозы (практически 70% веса). Чтобы сладость не казалась слишком приторной к ней добавляют кислоты, например, лимонную. 🍭 Сложнее остальных сладостей готовятся ириски. Чтобы их получить необходимо упаривать сахар, молоко и жир. При этом помимо перемешивания и сплавления идут реакции Майарда (сахар с аминокислотами) и карамелизации (частичная потеря воды сахарами). 🍫 Если конфеты дешёвые, то скорее всего их изготовили из "патоки", а не сахара. Вместо жира использовали пальмовое масло или маргарин.. Применявшийся ранее желатин (белок) постепенно заменили на пектины (растительные полисахариды). 🍬 Сегодняшние конфеты, помимо экстремальной калорийности (карамелька ~ тарелка овсяной каши), содержит малополезные компоненты. Это и опасные для сердца транс-ненасыщенные кислоты из кондитерского жира, и канцерогенные гетероциклы из перегретой патоки, и аллергичные ароматизаторы/красители. 🍴 Хотите сладкого? Съешьте фрукт. Мало? Возьмите мед или сделайте конфету из плавленного сахара с добавкой варенья. Хотите шоколада?Покупайте с 80+% какао. Остальной - смесь кондитерского жира и патоки с коричневым красителем и ароматизатором «шоколад».

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NEUTRAL

rus

NOT SPAM

СВЧ-печи Сегодня разберём один из самых популярных мифов связанный с излучением. А именно опасны ли для жизни человека микроволновые печи? Излучения бояться очень многие люди. Однако не все знают, что практически любой предмет излучает. Солнце, диван и даже люди. Энергия дивана или человека обычно небольшая, и зависит от температуры. Гамма и рентгеновское излучение - смертельно опасны , они несут много энергии и разрушают связи в молекулах, в том числе, ДНК. Световые и тепловые волны не так опасны, но и они способны нагреть и даже поджечь предмет, если сфокусировать. Микроволновая печь - это электрический ящик, который разогревает водосодержащие вещества, благодаря электромагнитному излучению дециметрового диапазона. Главное предназначение микроволновки это быстро разогревать, размораживать и готовить еду. В печи происходит диэлектрический нагрев материалов, которые содержат полярные молекулы . Энергия электромагнитных колебаний происходит благодаря электрическому движению молекул, обладающих дипольным моментом,который приводит к увеличению температуры материала. У СВЧ-печи есть несколько опасностей. Ни в коем случае не запускайте печку с поврежденной сеткой на дверце или снятой крышкой. Без клетки Фарадея излучение очень опасно. ДНК не повредится (как любят пугать горе-блогеры), энергетика не та, а вот сварить мозг насмерть может. То же самое с гаджетами. Магнетрон способен сжечь практически любую сложную электронику.

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https://t.me/s/ychemistry

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NEUTRAL

rus

NOT SPAM

Реакция перманганата калия с перекисью водорода.

https://t.me/chemistrytg2021/9563?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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NEUTRAL

rus

NOT SPAM

Разница в плотности вольфрама и магния.

https://t.me/chemistrytg2021/9564?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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NEUTRAL

rus

NOT SPAM

Макросъёмка кремниевой зажигалки

https://t.me/chemistrytg2021/9565?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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NEUTRAL

rus

NOT SPAM

Запатентован простой способ создания самоочищающихся покрытий Специалисты ФИЦ «Институт катализа СО РАН» запатентовали простой способ нанесения фотоактивных покрытий на поверхность материалов для самоочистки от микроорганизмов и токсических соединений. Обычно такие материалы изготавливают с изначально включенными в их структуру активными компонентами, а новый метод позволяет формировать тонкий слой фотокатализатора на поверхности уже готовых изделий. Разработанные в ИК СО РАН фотокатализаторы эффективны в широком спектральном диапазоне, включая УФ-излучение и видимый свет. https://mendeleev.info/zapatentovan-prostoj-sposob-sozdaniya-samoochishhayushhihsya-pokrytij/

https://t.me/chemrussia/5197?embed=1&mode=tme

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В Академии наук рассказали, как будет проходить экспертиза учебников Первая партия учебников поступила на экспертизу в РАН. Она включает девять единиц по обязательным предметам — физике, химии, биологии и другим школьным дисциплинам, сообщил нашему изданию глава комиссии РАН по экспертизе федеральных государственных образовательных стандартов и учебников, вице-президент РАН, академик Степан Калмыков. В ближайшую пятилетку ученые проверят 291 учебник, чтобы к 2029 году сформировать линейку единых государственных учебников по всем обязательным школьным дисциплинам. Подробнее в ПГ: https://www.pnp.ru/politics/v-akademii-nauk-rasskazali-kak-budet-prokhodit-ekspertiza-uchebnikov.html #инфраструктуранауки

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На сайте Научной электронной библиотеки Elibrary.ru опубликован очередной номер Журнала неорганической химии (том 69, № 7, 2024 г.) Содержание выпуска со ссылками на статьи: Синтез и свойства неорганических соединений Синтез Bi1.5CoSb1.5O7 со структурой пирохлора в гидротермальных условиях и его каталитические свойства в реакции окисления СО. Егорышева А.В., Голодухина С.В., Либерман Е.Ю., Разворотнева Л.С., Кирдянкин Д.И., Попова Е.Ф. Синтез ферромагнитных сплавов системы InSb-Ni2-YMnSb (Y = 0, 1). Пашкова О.Н., Овешников Л.Н., Риль А.И., Дмитряков П.В., Саныгин В.П. Новый литийвольфрамофосфат: синтез и кристаллическая структура. Каталитические свойства тетраядерного комплекса кобальта с вольфрамофосфатными лигандами и литиевыми противокатионами в реакции фотохимического окисления воды. Джабиева З.М., Шилов Г.В., Авдеева Л.В., Савиных Т.А., Джабиев Т.С. Синтез, структура и магнитные свойства Mn-замещенного магнетита для магнитореологических материалов. Гайдук Ю.С., Коробко Е.В., Радкевич Л.В., Голодок Р.П., Усенко А.Е., Паньков В.В. Поликатионные перовскиты в системе Ba2Y2O5-BaCuO2-BaMoO4-BaTiO3. Смирнова М.Н., Копьева М.А., Нипан Г.Д., Никифорова Г.Е., Япрынцев А.Д., Архипенко А.А. Влияние метода синтеза на морфологию и функциональные свойства обогащенных литием слоистых оксидов. Медведева А.Е., Махонина Е.В., Клименко М.М., Политов Ю.А., Румянцев А.М., Коштял Ю.М., Головешкин А.С., Курлыкин А.А. Координационные соединения Полимерные иодовисмутаты Cat{[BiI4]} с катионами - производными пиридина: строение и свойства. Шенцева И.А., Усольцев А.Н., Коробейников Н.А., Корольков И.В., Соколов М.Н., Адонин С.А. Кристаллические структуры двух полиморфных модификаций и термодинамические параметры парообразования бис-гептафторметилоктандионата меди. Стабников П.А., Беспятов М.А., Корольков И.В., Сухих А.С., Плюснин П.Е., Трубин С.В., Сартакова А.В., Сысоев С.В. Трехмерные металл-органические координационные полимеры Zn(II) на основе 1,2-бис(4-пиридил)этилена и анионов иодтерефталевой и иодизофталевой кислот. Загузин А.С., Бондаренко М.А., Коробейников Н.А., Усольцев А.Н., Федин В.П., Адонин С.А. Иодидные комплексы Cd(II) с 2-галогензамещенными пиридинами: структура и особенности галогенной связи в твердом теле. Адонин С.А., Новиков А.С. Синтез и термические превращения комплексов вольфрамофосфатометаллатов с гексаметилентетрамином. Лозинский Н.С., Лопанов А.Н., Мороз Я.А., Пехтерева Т.М. Физико-химический анализ неорганических систем Исследование сокристаллизации сульфатов неодима и стронция в отсутствие ионов калия. Бушуев Н.Н., Татосян Г.К. Фазовые равновесия в четырехкомпонентной системе NaF-NaCl-Na2MoO4-Na2WO4. Матвеев А.А., Сухаренко М.А., Гаркушин И.К. Фазовые равновесия, кристаллическая структура и кислородная нестехиометрия сложных оксидов, образующихся в системе GdCOO3-SrCOO3-δ-SrFeO3-δ-GdFeO3. Аксенова Т.В., Соломахина Е.Е., Урусова А.С., Черепанов В.А. Физикохимия растворов Комплексное выщелачивание Li, Fe, Al и Cu из активных материалов LFP аккумуляторов. Саломатин А.М., Зиновьева И.В., Заходяева Ю.А., Вошкин А.А. Неорганические материалы и наноматериалы Синтез наночастиц оксида цинка при переработке гальванических шламов. Мурашова Н.М., Купцова М.Ю., Токарев П.О. Оптическая керамика, полученная горячим прессованием порошка CVD-ZnSe. Балабанов С.С., Тимофеева Н.А., Евстропов Т.О., Косьянов Д.Ю., Наумова А.В., Филофеев С.В. #российскаянаука #ионх

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NEUTRAL

rus

NOT SPAM

Новый материал с невероятной стойкостью к различным жидкостям 🦠 💧 🧪 Учёные сделали важный прорыв в области материаловедения: они создали поверхность, которая практически не смачивается никакими жидкостями! 🤯 Это значит, что вода, масла и даже самые «липкие» растворы не смогут удержаться на ней. В чём фишка? 🔬 Исследователи применили особую наноструктурированную текстуру и уникальный химический состав поверхности. 🌱 Этот подход позволяет максимально снизить энергию взаимодействия материала с жидкостью, превращая любую каплю в упругий шарик, скатывающийся с поверхности. Зачем это нужно? ⚙️ Антикоррозийные покрытия 🦠 Самоочищающиеся поверхности — от экранов смартфонов до медицинских имплантов 🚀 Новые способы обработки промышленных деталей и оборудования Оригинальная статья: Phys.org

https://t.me/incredible_chemistry/383?embed=1&mode=tme

https://t.me/

https://t.me/s/incredible_chemistry

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NEUTRAL

rus

NOT SPAM

🍷 🔬 Почему от красного вина болит голова? Химический детектив в бокале! 🕵️‍♂️ Вы когда-нибудь задумывались, почему после бокала красного вина иногда начинает болеть голова? 🤔 Давайте разберёмся в этом с точки зрения химии! 🧪 Виновник торжества: кверцетин 🎭 Красное вино богато кверцетином — флавоноидом, который придаёт напитку насыщенный цвет и вкус. Однако, как выяснили учёные, этот же кверцетин может стать причиной головной боли. При попадании в организм он превращается в кверцетин-глюкуронид, который блокирует фермент альдегиддегидрогеназу (ALDH2). Этот фермент отвечает за разложение ацетальдегида — токсичного продукта распада этанола. Когда ALDH2 блокируется, ацетальдегид накапливается, вызывая неприятные симптомы: головную боль, покраснение лица и тошноту. Интересный факт: уровень кверцетина в вине зависит от условий выращивания винограда. Например, виноград, выращенный под ярким солнцем, накапливает больше кверцетина. Поэтому некоторые сорта красного вина могут содержать его в 4–5 раз больше среднего уровня. Что делать? 🤷‍♀️ Если вы склонны к головным болям после красного вина, попробуйте: - Выбирать белое вино: в нём содержится меньше кверцетина. - Ограничить количество: иногда меньше — значит лучше. - Обратить внимание на сорта: некоторые красные вина содержат меньше кверцетина. И помните, всё хорошо в меру! 🥂 Поделитесь этой информацией с друзьями, чтобы они тоже узнали, что химия может объяснить даже такие жизненные загадки!* 😉

https://t.me/incredible_chemistry/384?embed=1&mode=tme

https://t.me/

https://t.me/s/incredible_chemistry

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NEUTRAL

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ИНКРЕТИНЫ. Почему снижают вес? Итак, на прошлых уроках ⤴️ мы узнали с вами, что после попадания углеводной пищи в ЖКТ из клеток слизистой выделяются специфические гормоны инкретины: ГПП-1 и ГИП, которые усиливают действие инсулина, и быстрее снижают свободную глюкозу в плазме крови, направляя ее на различные метаболические пути. ❓ Но почему сегодня инкретины используют не только для лечения сахарного диабета, но и для лечения ожирения? 👨‍⚕️ А все дело в том, что ГПП-1 и ГИП проникают через гемато-энцефалический барьер и возбуждают центр насыщения в вентромедиальном гипоталамусе. Простым языком они выключают аппетит, как бы нажимая кнопку «выкл». Нет желания кушать, нет избытка субстрата для накопления жировой массы. А почему человек худеет? 🧐 На саму жировую ткань инкретины никак не влияют. Работает классический биохимический процесс. Просто в период дефицита пищи запускаются процессы использования эндогенных энергетических запасов: сперва гликогена, далее жировой ткани, частично белковых депо. А вы знали об этом? 😎

https://t.me/simplebestbiochemistry/549?embed=1&mode=tme

https://t.me/

https://t.me/s/simplebestbiochemistry

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https://t.me/s/ychemistry

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NEUTRAL

rus

SPAM

Чем мы чистим зубы? С детства нас учили тому, что утром и вечером нужно чистить зубы 👄 . Следуя правилам и привычкам, ежедневно два раза в день, мы это делаем. При этом мало кто из нас обращает внимание на состав зубной пасты. Мы слепо верим рекламе и даже не пытаемся выяснить, действительно ли данное средство защищает зубы от налёта, кариеса и прочих проблем. Интересный факт. Наши далекие предки 🐵 , которые даже не знали про существование "быстрых" углеводов, жили без кариеса до 30-40 лет. Сегодня же кариес появляется даже у детей 👶 до 5 лет. 🔬 Любая зубная паста состоит из четырех видов компонентов: абразивные, поверхностно-активные, связующие и вспомогательные. Абразивные вещества - одни из самых главных, они убирают налёт, в котором обычно размножаются бактерии. Когда-то для этих целей использовали зубной порошок, однако из-за того, что у большинства людей чувствительная эмаль, его запретили. Сегодня эффект своеобразной "терки" создаётся благодаря полимерным силикатам. Секрет "отбеливающих" паст заключается в обыкновенной пищевой соде. Поэтому если вы любитель отбеливающей пасты, рекомендую использовать её не чаще трёх раз в неделю. Кристаллы соды довольно твёрдые, поэтому могут повредить эмаль. Содержащиеся в зубных пастах ПАВ отвечают за пенообразование 🌊 , чистящий эффект и уменьшение вероятности появления микроцарапин на эмали. По статистике, люди больше любят пенящиеся зубные пасты. Поэтому практически в каждом тюбике есть ПАВ. Связующие компоненты, вроде карбоксиметилцеллюлозы, нужны для того, чтобы паста была именно пастой, а не жидкостью 💧 . Так что можем считать данный ингредиент своего рода загустителем. У любой зубной пасты есть 2 главные задачи - стерилизация полости рта 👅 и реминерализация зубов. За первое отвечают различные экстракты трав 🌿 , за второе - соединения кальция и фтора. По последним исследованиям, кальций в зубной пасте бесполезен, а вот ионы фтора, действительно, успевают проникнуть в эмаль и ее укрепить. Лучше не использовать пасты с антибиотиками, часть всегда попадает в желудок и убивает наших симбионтов. Кроме того, бесконтрольное использование бактерицидов ускоряет эволюцию бактерий, а так можно вывести совсем неубиваемого микроба. Прямо у себя во рту 😕 . Поэтому стоматологи и химики рекомендуют использоваться зубные пасты с экстрактами трав 🌿 . Помимо запаха они могут обладать противовоспалительным и бактериостатичным эффектом: десны быстрее успокаиваются и бактерии хуже размножаются.

https://t.me/ychemistry/1056?embed=1&mode=tme

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https://t.me/s/ychemistry

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Демонстрация идеального сочетания магнитной левитации и электромагнитной индукции.

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https://t.me/s/chemistrytg2021

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NEUTRAL

rus

NOT SPAM

Окислительно-восстановительная реакция пероксида натрия с серой: 2Na2O2 + S = 2Na2O - SO2.

https://t.me/chemistrytg2021/9561?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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NEUTRAL

rus

NOT SPAM

Добавление твердой ртути в теплую воду Ртуть-единственный металл, который является жидким при комнатной температуре. Как только он остынет ниже -39°C, он замерзнет. Плавление его выглядит очень круто, потому что оно имеет очень высокое поверхностное натяжение и образует красивые сферы.

https://t.me/chemistrytg2021/9562?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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[{"ner":"39","lemma":"39","label":"NUM","start_pos":145,"end_pos":147}]

NEUTRAL

rus

NOT SPAM

Влияние синтетических условий на координационные соединения с магнитными свойствами Международный коллектив ученых из Крымского федерального университета им. В.И. Вернадского, Института общей и неорганической химии им Н.С. Курнакова РАН, Федерального исследовательского центра проблем химической физики и медицинской химии РАН и Венского технологического университета (Австрия) синтезировал две формы комплекса Co(II) с анионами 4-[(2-фторанилино)-фенил-метилен]-5-метил-2-фенил-3-пиразолона - безводный CoL2 из Co(OAc)2 и водный CoL2(H2O)2 из Co(OAc)2⸱4H2O. Показано, что координация двух молекул воды к металлоцентру влияет на симметрию кристаллического поля иона кобальта (II) посредством модификации координационного полиэдра с искаженного тетраэдра на искаженный октаэдр и кардинально меняет магнитные характеристики. Магнетохимические исследования позволили определить тип магнитной анизотропии – легкоосевая для CoL2 и легкоплоскостная для CoL2(H2O)2, теоретические ab initio расчеты выявили причину возникновения медленной магнитной релаксации в каждом случае. Наличие осевой магнитной анизотропии в CoL2 выражено проявлением медленной магнитной релаксации, индуцированная полем 0.05 Т, реализуемой по механизму Орбаха с эффективным барьером перемагничивания 79 K, в комбинации с механизмами Рамана и прямого. Таким образом, детальное изучение влияния синтетических условий на образующиеся координационные соединения с определенными магнитными параметрами, приближает возможность создания компонентов устройств хранения сверхплотной записи данных и логических кубитов. Результаты работы опубликованы в журнале "Polyhedron". A. Gusev, Yu. Baluda, A. Matiukhina, M. Kiskin, W. Linert. Coordination number impact on magnetic properties of Schiff base Co(II) complexes. // Polyhedron, 2024, 117074; DOI: 10.1016/j.poly.2024.117074 https://doi.org/10.1016/j.poly.2024.117074 #российскаянаука #ионх

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https://t.me/s/chemrussia

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NEUTRAL

rus

SPAM

Антиферромагнитные взаимодействия в димере кобальта с мостиковым бирадикалом Ученые из Международного томографического центра СО РАН, Института неорганической химии имени А.В. Николаева СО РАН совместно с коллегами из Франкфуртского университета им. Иоганна Вольфганга Гёте и Технологического института Карлсруэ (Германия) получили новый комплекс на основе кобальта состава {(hfac)CoII(BN)CoII(hfac)} (hfac = гексафторацетилацетонат, BN = бис-нитроксид) и изучили его строение и свойства. Данные магнетометрии свидетельствовали о наличии спин-фрустрации в димере и сильной АF связи между ионом кобальта и бирадикалом. Выполненные исследования позволили разработать оригинальный теоретический подход к определению диапазона возможных значений обоих типов обменных интегралов. Ab initio расчеты магнитных кривых хорошо согласуются с экспериментом. Результаты работы опубликованы в журнале Magnetochemistry и могут быть использованы для дизайна молекулярных магнитных материалов. Morozov V.A., Peresypkina E.V., Wernsdorfer W., Vostrikova K.E. Strong Antiferromagnetic Interactions in the Binuclear Cobalt(II) Complex with a Bridged Nitroxide Diradical // Magnetochemistry 2024, 10, 11, 82. https://www.mdpi.com/2312-7481/10/11/82 Источник: ИНХ СО РАН #российскаянаука

https://t.me/chemrussia/5192?embed=1&mode=tme

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На сайте научной электронной библиотеки eLibrary.ru опубликован очередной номер журнала «Координационная химия» (2024, Том 50, № 9) Содержание номера со ссылками на статьи: Развитие химии кластеров, супрамолекулярной химии и химии металл-органических координационных полимеров в научной школе чл.-корр. РАН В.П. Федина. Соколов М.Н., Дыбцев Д.Н. https://www.elibrary.ru/item.asp?id=75090227 3,6-дипиридил-1,2,4,5-тетразин в синтезе металл-органических координационных полимеров цинка и кадмия с лигандами анилатного типа. Трофимова О.Ю., Колеватов Д.С., Дружков Н.О., Малеева А.В., Якушев И.А., Дороватовский П.В., Пискунов А.В. https://www.elibrary.ru/item.asp?id=75090228 Масштабируемый способ нанесения потенциальных кубитов на поверхность МОКП MOF-808 Томилов А.С., Язикова А.А., Мельников А.Р., Смирнова К.А., Порываев А.С., Федин М.В. https://www.elibrary.ru/item.asp?id=75090229 Кадмий(II)-органические координационные полимеры с полиядерным блоком: контроль размерности и люминесцентный отклик на пиридин. Дубских В.А., Лысова А.А., Самсоненко Д.Г., Дыбцев Д.Н. https://www.elibrary.ru/item.asp?id=75090230 Синтез, кристаллическая структура и магнитные свойства координационных полимеров кобальта(н) с 4,7-ди(1,2,4-триазол-1-ил)-2,1,3-бензотиадиазолом и ароматическими дикарбоновыми кислотами. Павлов Д.И., Лавров А.Н., Самсоненко Д.Г., Потапов А.С. https://www.elibrary.ru/item.asp?id=75090231 Синтез, строение и спектрально-люминесцентные свойства нейтрального тряс-комплекса Tb (III) С 4,4,5,5,6,6,6-гептафтор-1-(1-метил-1я-пиразол-4-ил) гексан-1,3-дионом. Тайдаков И.В., Метлин М.Т., Метлина Д.А., Гончаренко В.Е., Власова Т.С. https://www.elibrary.ru/item.asp?id=75090232 Кластерный иодид рения Re3I9 как прекурсор в синтезе [Re(CO)5I] И ((Н-C4H9)4N)2[Re2Cl8]. Горбачук Е.В., Михайлов М.А., Шевень Д.Г., Соколов М.Н., Яхваров Д.Г. https://www.elibrary.ru/item.asp?id=75090233 Синтез и строение полимерных карбоксилатов кальция. Самулионис А.С., Воронина Ю.К., Мельников С.Н., Гавронова А.С., Утепова Д.А., Гоголева Н.В., Головешкин А.С., Ямбулатов Д.С., Николаевский С.А., Кискин М.А., Еременко И.Л. https://www.elibrary.ru/item.asp?id=75090234 #российскаянаука #ионх

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https://t.me/s/chemrussia

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В связи с успешным проведением XXII Менделеевского съезда по общей и прикладной химии, посвященного 300-летию РАН и 190-летию со дня рождения Д.И. Менделеева под эгидой Международного союза теоретической и прикладной химии (IUPAC), Президиум РАН объявил благодарность членам РАН - членам Организационного комитета Съезда и руководителям секций и симпозиумов, а также работникам РАН. #российскиеученые #инфраструктуранауки

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Если кто захочет самостоятельно синтезировать это чудо - https://pubs.acs.org/doi/epdf/10.1021/acs.jafc.4c04849?ref=article_openPDF

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https://t.me/

https://t.me/s/incredible_chemistry

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NEUTRAL

other

NOT SPAM

В 1924 году Нобелевскую премию по химии вручили.. никому. Нобелевский комитет решил. что достойных нет. Вот так...

https://t.me/incredible_chemistry/379?embed=1&mode=tme

https://t.me/

https://t.me/s/incredible_chemistry

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[{"ner":"Нобелевский комитет","lemma":"нобелевский комитет","label":"ORG","start_pos":58,"end_pos":77},{"ner":"1924","lemma":"1924","label":"NUM","start_pos":2,"end_pos":6}]

NEUTRAL

rus

NOT SPAM

Запах трупного цветка раскрыт Химические вещества, вызывающие сильный запах гнили у «трупного цветка» (Amorphophallus titanum) — растения из джунглей, которое цветёт только раз в несколько лет и пахнет как открытая могила, — были идентифицированы учёными. Неприятный запах гигантского цветка предназначен для привлечения опыляющих насекомых, особенно жуков-навозников, которые питаются падалью и откладывают яйца в трупах животных. Новое исследование предполагает, что растение эволюционировало, чтобы распространять свой запах как можно дальше. Исследователи обнаружили, что характерный запах исходит от вещества путресцина (1,4-диаминобутан) — диамина, образующегося при расщеплении аминокислоты аргинина, которая придаёт запах гниющему мясу, — и химических веществ диметилдисульфида и диметилтрисульфида, которые цветок вырабатывает из аминокислоты метионина, содержащей серу. Биолог-растениевед из Дартмутского колледжа Эрик Шаллер, который руководил исследованием, говорит, что путресцин составляет основу запаха, в то время как смесь двух соединений серы может пахнуть аналогично, но на гораздо большем расстоянии. Исследование основано на изучении двух цветков — одного в 2016 году, а другого в 2022 году — 21-летнего трутовика под названием Морфи, который сейчас растёт в теплице Дартмутского колледжа. Когда цветёт одиночный цветок, «мы чувствуем запах по всему зданию», — говорит Шаллер. — «Запах чувствуется довольно далеко». В ходе исследования Шаллеру иногда приходилось проводить целые ночи, измеряя температуру цветка, для чего он держал в своём кабинете отдельную рубашку. «От твоей одежды воняет», — говорит он, добавляя, что его жена приказала вынести её из дома после полевых работ, потому что она так сильно пахла. Впервые учёные обнаружили цветок-труп в тропическом лесу на индонезийском острове Суматра в 1878 году. В дикой природе он цветёт нечасто, но популярен в ботанических садах.

https://t.me/incredible_chemistry/380?embed=1&mode=tme

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https://t.me/s/incredible_chemistry

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💊 Химики-кулинары: как студенты превращают лаборатории в нарколаборатории 🍸 🧪 Мексиканские картели, похоже, нашли способ оживить скучное расписание студентов-химиков, превратив их в настоящих «мэтров» органического синтеза. Неудивительно, ведь что может быть лучше, чем лабораторная практика, за которую не просто ставят зачет, а еще и платят? Правда, вместо диплома об окончании в награду — место в криминальной хронике. Как сообщает статья New York Times , вербовщики картелей — настоящие мастера PR. Появляясь на кампусах, они шепчут в уши студентам обещания «интересной работы» и «высокой зарплаты». Прямо как рекрутеры крупных корпораций, только с меньшим акцентом на корпоративные ценности и больше — на скорость реакции при слове «полиция». Один из студентов вспоминает, как к нему подошел «инвестор» с классическим предложением: «Вы делаете замечательные опыты. Хотите попробовать себя в сфере, где ошибки буквально на вес золота?». Видимо, каждый второй химик в Мексике мечтает превратить лабораторный стол в стартовую площадку наркокартеля. Профессора тоже не остаются в стороне от новых тенденций. Один преподаватель из Синалоа признался, что студенты с энтузиазмом интересуются синтезом «нестандартных» веществ. «Профессор, а когда мы будем изучать кокаин?» — спросил один особо целеустремленный студент. Очевидно, в его понимании органическая химия — это билет в «Breaking Bad: латиноамериканская версия». Картели, конечно, остро нуждаются в таких «талантах». Кто же еще научит их, как «повысить качество продукции» и «оптимизировать производственный процесс»? Ведь настоящая проблема фентанила не в том, что он уничтожает жизни, а в том, что его формула не совершенна. Сарказм, если кто-то не заметил. Итак, студенты-химики, если вас вдруг пригласят на «закрытый научный семинар» с обещаниями щедрых гонораров, помните: бесплатный сыр бывает только в мышеловке. И да, мышеловка эта обычно располагается где-то между тюрьмой и еще более мрачными перспективами.

https://t.me/incredible_chemistry/382?embed=1&mode=tme

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https://t.me/s/incredible_chemistry

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[{"ner":"New York Times","lemma":"new york times","label":"ORG","start_pos":442,"end_pos":456},{"ner":"Мексике","lemma":"мексика","label":"LOC","start_pos":971,"end_pos":978},{"ner":"Синалоа","lemma":"синалоа","label":"LOC","start_pos":1131,"end_pos":1138},{"ner":"Breaking Bad","lemma":"breaking bad","label":"ORG","start_pos":1377,"end_pos":1389}]

NEUTRAL

rus

NOT SPAM

ОЗЕМПИК. Гормоны инкретины Пожалуй трудно найти сегодня тех, кто не слышал про данное лекарство. Препарат, совершивший прыжок в лечении ожирения, давший возможность многим пациентам эффективно снизить избыточную массу тела. 👨‍⚕️ Но давайте попробуем с точки зрения биохимии разобраться в механизмах и эффектах данного препарата. Итак, «оземпик» или семаглутид относится к агонистам рецепторов ГПП-1. В чем суть ❓ После приема углеводистой пищи наш грамотный организм стремится снизить ⤵️ уровень глюкозы с помощью гормона инсулина. Но у инсулина есть помощники - пептидные гормоны из семейства инкретинов: глюкагоноподобный пептид - 1 (ГПП-1) и глюкозозависимый инсулинотропный пептид (ГИП). Поговорим про первый из них. После попадания углеводистой пищи в тонкий и толстый кишечник, специфические клетки слизистой - L клетки - улавливают свободную глюкозу и вырабатывают гормон ГПП 1, которые далее попадает в плазму крови и воздействует на свои рецепторы. Данный гормон имеет много специфических эффектов, но ключевой - торможение секреции глюкагона (повышающий уровень глюкозы) и стимуляция секреции и эффектов инсулина. ❗️ Тем самым глюкоза быстрее попадает в клетки, метаболизируется по своим путям, а уровень свободной глюкозы в плазме крови снижается эффективнее. Также данный гормон действует на центр голода, тормозя его и быстрее вызывая чувство насыщения. ✔️ А вот «оземпик» фактически является аналогом ГПП-1. Отсюда его сахароснижающий эффект становится понятен, но почему он еще эффективно помогает снизить избыточную массу тела? А Об этом поговорим уже в следующем посте 😉 А пока расскажите, что вы знаете про данный препарат?

https://t.me/simplebestbiochemistry/545?embed=1&mode=tme

https://t.me/

https://t.me/s/simplebestbiochemistry

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NEUTRAL

rus

NOT SPAM

Друзья, продолжаю вчерашнюю тему, давайте решим небольшую задачу! Одному пациенту 50 мл 20% раствора глюкозы было введено внутривенно, другой пациент принял тот же объем раствора глюкозы перорально. В каком случае уровень глюкозы вернется в норму быстрее? Выберите тот вариант, который вы считаете верным и расскажите в комментариях почему 😊 Чуть позже я расскажу и поясню правильный ответ!

https://t.me/simplebestbiochemistry/546?embed=1&mode=tme

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https://t.me/s/simplebestbiochemistry

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[{"ner":"50","lemma":"50","label":"NUM","start_pos":82,"end_pos":84},{"ner":"20","lemma":"20","label":"NUM","start_pos":88,"end_pos":90}]

NEUTRAL

rus

NOT SPAM

Итак, правильный ответ ⤴️ Глюкоза снизится в плазме крови быстрее именно при пероральном приеме. А все дело в эффектах гормонов инкретинов . @milanastern ответила абсолютно верно! Да, рассуждая здравым смыслом и логикой, хочется сказать, что при внутривенном введении глюкоза снизится быстрее, поскольку она одномоментно стимулирует выработку гормона инсулина, который снижает свободную глюкозу в плазме. Но на деле процесс работает несколько иначе. При пероральном приеме концентрированный 20% раствор глюкозы, во-первых, стимулирует секрецию клетками ЖКТ инкретинов в кровь: ГПП-1 и ГИП, а также, быстро всасываясь в плазму, вызывает выработку гормона инсулина из b-клеток поджелудочной. 👨‍⚕️ Но в присутствии инкретинов эффекты инсулина оказываются активнее, а секретируется он быстрее. Также тормозится выделение глюкагона, который всегда имеется в определенной базальной концентрации в крови. ❗️ Поэтому именно при приеме глюкозы per os гликемия вернется быстрее в норму. Поэтому препараты инкретиновой терапии используются для лечения сахарного диабета 2 типа, например, тот же самый «оземпик». 😉

https://t.me/simplebestbiochemistry/548?embed=1&mode=tme

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https://t.me/s/simplebestbiochemistry

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NEUTRAL

rus

NOT SPAM

🍅 Томатный сок и бром В состав сока входит соединение под названием ликопин, который делает томаты красными. В ходе реакции с бромом все его одиннадцать двойных связей последовательно бромируются, из-за чего происходит многократное изменение цвета. В результате мы можем увидеть целую палитру красок по всей высоте цилиндра.

https://t.me/ychemistry/1049?embed=1&mode=tme

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https://t.me/s/ychemistry

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NEUTRAL

rus

NOT SPAM

Что происходит с алкоголем в организме? 🍸 Какие химические превращения происходят со спиртом при попадании в организм человека? Почему наступает похмелье? И какими лекарствами лечат алкоголизм? 👩🏻‍🔬 Думаю, формула этанола вам хорошо знакома — CH₃CH₂OH . При попадании алкоголя в организм, спирт окисляется сразу тремя ферментами. Самое активное действие в этом процессе принимает алкогольдегидрогеназа . Попробуйте хоть разок прочитать это длинное название 😉 В дальнейшем будем использовать сокращение АЛДГ . В результате действия ключевого фермента спирт превращается в уксусный альдегид . Его формулу CH₃CHO можно представить, как этиловый спирт, от которой отщепилась одна молекула воды. Именно уксусный альдегид становится причиной похмелья и всех токсических эффектов . К счастью, альдегид является промежуточным продуктом расщепления, и дальше за дело берётся другой фермент – ацетальдегидрогеназа (АДГ) . Если с первого взгляда вам показалось, что это длинное название не отличается от упомянутого выше, то прочитайте их еще раз и вы заметите разницу. АДГ превращает уксусный альдегид в относительно безопасную уксусную кислоту CH₃COOH , которая в дальнейшем на клеточном уровне окисляется до углекислого газа CO₂ и воды H₂O и выводится из организма . При избытке алкоголя в крови ферменты не справляются с полным превращением альдегида в уксусную кислоту, в результате он накапливается в организме. Причем альдегид в десятки раз в 10—30 токсичнее самого этилового спирта. Когда к утру организм не успевает расправиться с ацетальдегидом, наступает похмелье 🥴 А теперь представьте себе такое вещество, которое будет блокировать действие АДГ . Фермент перестанет выполнять свою функцию по обезвреживанию вредного альдегида — его концентрация в организме выпившего человека вырастает в несколько раз, чем обычно при такой же дозе алкоголя. При этом гарантированно начнется рвота, головокружение и острая головная боль — все самые неприятные симптомы похмелья 🤮 Таким веществом является дисульфирам , который используют при медикаментозном лечении алкоголизма . Пациенту, принимающему дисульфирам, под контролем врача дают выпить небольшое количество спиртного. Так как ферменты окисления этанола заблокированы , в организме накапливается ацетальдегид и возникает острая интоксикация , которая сопровождается неприятными, болезненными ощущениями 🤢 В результате формируется условно-рефлекторная реакция отвращения к вкусу и запаху этанола. Помимо лечения алкогольной зависимости, исследуется эффективность дисульфирама и его производных в качестве противоопухолевых препаратов 💊 В ряде исследований обнаружено, что в сочетании с некоторыми металлами дисульфирам ускоряет естественный процесс смерти клеток, приостанавливая рост опухоли и метастаз . Теперь вы имеете представление о том, какой путь проделывает алкоголь после попадания в организм. Лучше получайте удовольствие от живого общения без лишних бокалов с напитками 🥂

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[{"ner":"АЛДГ","lemma":"алдг","label":"ORG","start_pos":502,"end_pos":506},{"ner":"CH₃CHO","lemma":"ch₃cho","label":"ORG","start_pos":603,"end_pos":609},{"ner":"АДГ","lemma":"адг","label":"ORG","start_pos":905,"end_pos":908},{"ner":"CH₃COOH","lemma":"ch₃cooh","label":"ORG","start_pos":1135,"end_pos":1142},{"ner":"АДГ","lemma":"адг","label":"ORG","start_pos":1643,"end_pos":1646},{"ner":"10—30","lemma":"10—30","label":"DATE","start_pos":1439,"end_pos":1444},{"ner":"₃","lemma":"₃","label":"NUM","start_pos":245,"end_pos":246},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":248,"end_pos":249},{"ner":"₃","lemma":"₃","label":"NUM","start_pos":605,"end_pos":606},{"ner":"₃","lemma":"₃","label":"NUM","start_pos":1137,"end_pos":1138},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":1219,"end_pos":1220},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":1229,"end_pos":1230},{"ner":"30","lemma":"30","label":"NUM","start_pos":1442,"end_pos":1444}]

NEUTRAL

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Что внутри неоновых ламп? 🏮 Из чего они состоят? Всё довольно-таки примитивно: стеклянная трубка, заполненная инертным газом, и два электрода на её концах . Тут стоит отметить, что правильно называть такие лампы не неоновыми, а газосветными , потому что в качестве инертного газа может выступать не только неон. Выбор состава газа зависит от желаемого цвета свечения. Гелий даёт бело-оранжевый оттенок 💛 , неон — красновато-оранжевый ❤️ , а ксенон и криптон дают холодное синеватое свечение 💙 . Также на цвет влияют частота и плотность тока: меняя эти параметры можно смещать свечение в синюю или красную область спектра. По какому принципу происходит свечение? К электродам подводится ток с таким напряжением, чтобы его хватило сорвать с молекулы газа электрон. Мы получаем положительно заряженную частицу, которая по известному принципу движется к отрицательно заряженному электроду, а сам электрон с зарядом «минус» бежит к «плюсу». Всё по известному принципу: противоположности притягиваются . В трубке происходит упорядоченное движение заряженных частиц — газ проводит электрический ток . Соударяясь между собой, нейтральные молекулы и заряженные частицы постоянно обмениваются энергией. В ходе этого обмена частицы начинают излучать энергию в виде квантов света. В результате трубка начинает равномерно мягко светиться в спектре выбранного инертного газа. Поэтому такие лампы и называются газосветными — в них светится сам газ. 🧿 Этим они отличаются от своих сородичей по принципу работы — люминесцентных и электродосветных . Чтобы вы не запутались, мы сразу обозначим главные отличия. Люминесцентные лампы изнутри покрыты слоем люминофора — вещества, способного преобразовывать поглощаемую энергию в видимый свет. Это те самые длинные белые «джедайские мечи» на потолке в офисе, поликлинике или метро. А также их более компактные собратья, чаще принимаемые за энергосберегающие. Люминесцентные лампы обычно заполнены инертным газом и парами ртути. Но только проходящий электрический ток приводит к появлению УФ-излучения, которое само по себе невидимо для человеческого глаза, поэтому его преобразуют в видимый свет с помощью упомянутого люминофорного покрытия. В данном случае светится не газ, а люминофор ✨ В электродосветных лампах свечение исходит от электродов , которые так же возбуждаются энергией газового разряда. Но не стоит путать электродосветные источники с лампами накаливания, которые светятся за счёт нагрева до температуры каления проволоки из тугоплавкого металла 💡

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NEUTRAL

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Какая кислота самая сильная? Азотная HNO₃? А может быть серная H₂SO₄? Какие еще кислоты ты помнишь с уроков химии? 👩🏻‍🏫 На самом деле, существуют соединения, кислотные свойства которых в тысячи раз сильнее концентрированной серной кислоты — их называют суперкислотами . Прочитав этот пост, ты узнаешь о некоторых из них. Мы уже обсуждали меру кислотности — значение pH, — но при рассмотрении суперкислот бессмысленно опираться на водородный показатель, потому что он используется только для водных растворов и его диапазон строго ограничен. Для характеристики силы суперкислот была введена особая величина — параметр или функция кислотности Гаммета . Она и позволяет сравнивать свойства более экзотических соединений. Для 100% серной кислоты функция кислотности составляет 11,93 . Это значение является точкой отчёта — все вещества, для которых оно больше, относятся к суперкислотам 💪 К таким соединениям относится хлорная кислота HClO₄ . В чистом виде хлорная кислота является бесцветной дымящей жидкостью, но при длительном хранении она желтеет и становится взрывоопасной за счёт накопления оксида хлора Cl₂O₇. Соли хлорной кислоты используются в производстве взрывчатых веществ 💥 Безводная фторсерная кислота HSO₃F еще сильнее чем серная и хлорная вместе взятые. Это желтая, едкая и токсичная жидкость, которая разрушает многие вещества, устойчивые под действием обычных кислот — органические волокна и металлические поверхности. Её водные смеси способны растворять даже стеклянную посуду 🍽 Карборановые кислоты являются одними из самых сильных суперкислот , известных человеку, — эти соединения сильнее серной кислоты почти в десятки тысяч раз. Первые карборановые кислоты синтезировали в 2005 году в университете Калифорнии при участии сотрудников Российской академии наук. Карборановые кислоты обладают структурой икосаэдра — многогранника с 20 гранями — и за счёт этого являются стабильными веществами, которые можно хранить и использовать в лабораторных условиях 👩🏻‍🔬 «Магическая кислота» — смесь уже упомянутой фторсерной кислоты HSO₃F и фторида сурьмы SbF₅ . Эта смесь получила своё название после того, как на новогодней вечеринке один из сотрудников показал фокус с исчезновением свечи — он растворил её в «магической кислоте» 🧞‍♀️ . Исследование показало, что кислота настолько сильная, что способна расщепить молекулы парафинов, из которых состоит свеча. Оказалось, что она более чем в миллион раз сильнее, чем серная. Существуют и многие другие суперкислоты, каждая из которых представляют интерес для науки и производства. С их помощью удаётся запустить те реакции, которые или не идут совсем 🙅‍♀️ , или требуют экстремальных условий 🤷‍♀️ . Желаю тебе отличного дня! И помни, что серная кислота далеко не самая сильная 👀

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https://t.me/s/chemistrytg2021

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NEUTRAL

rus

NOT SPAM

Холодное пламя. Реакция изобутанола с эфиром бора.

https://t.me/chemistrytg2021/9555?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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NEUTRAL

rus

NOT SPAM

Галлий реагирует с алюминиевым замком, через некоторое время получается крайне хрупкий сплав, который легко разрушить.

https://t.me/chemistrytg2021/9556?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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[{"ner":"Галлий","lemma":"галлий","label":"PER","start_pos":0,"end_pos":6}]

NEUTRAL

rus

NOT SPAM

Цветные ферромагнитные дисплейные ячейки. Любопытное поведение возникает из-за взаимодействия между магнитной силой и поверхностным натяжением, приводящей к симметричным массивам шипов, когда жидкость пытается выровняться с силовыми линиями мощного неодимового магнита.

https://t.me/chemistrytg2021/9557?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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NEUTRAL

rus

NOT SPAM

Горячий древесный уголь и жидкий кислород.

https://t.me/chemistrytg2021/9558?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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NEUTRAL

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NOT SPAM

Метод индукционного детектирования магнитной динамики, вызванной температурными изменениями Ученые из Международного томографического центра СО РАН, Новосибирского государственного университета, Института ядерной физики им. Г.И. Будкера СО РАН, Института элементоорганических соединений им. А.Н. Несмеянова РАН и Института общей и неорганической химии им. Н.С. Курнакова РАН разработали метод индукционного детектирования магнитной динамики, вызванной температурными изменениями, который может быть эффективно применен для изучения молекулярных спиновых систем. Представлен общий дизайн и конструкция индукционного датчика. Для оценки эффективности метода были исследованы несколько координационных соединений VO2+, Co2+ и Dy3+ с использованием в качестве источника импульсного нагрева Новосибирского лазера на свободных электронах, генерирующего мощные импульсы излучения терагерцового диапазона. Зарегистрированная магнитная динамика качественно или количественно описана предложенной базовой теоретической моделью и сопоставлена с данными, полученными методом магнитометрии в переменном поле. Результаты работы, выполненной при поддержке РНФ (проект № 22-13-00376), опубликованы в журнале The Journal of Chemical Physics. Melnikov, A. R.; Ivanov, M. Y.; Samsonenko, A. A.; Getmanov, Y. V.; Nikovskiy, I. A.; Matiukhina, A. K.; Zorina-Tikhonova, E. N.; Voronina, J. K.; Goloveshkin, A. S.; Babeshkin, K. A.; Efimov, N. N.; Kiskin, M. A.; Eremenko, I. L.; Fedin, M. V.; Veber, S. L. // Inductive detection of temperature-induced magnetization dynamics of molecular spin systems // The Journal of Chemical Physics. 160 (2024) 22. https://doi.org/10.1063/5.0211936 #российскаянаука #ионх

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NEUTRAL

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Постановлением Президиума РАН премия им. Л.А. Чугаева РАН присуждена д.х.н. М.А. Кискину, д.х.н. А.А. Сидорову и чл.-корр. РАН В.К. Иванову за цикл работ «Координационная химия как основа для создания новых функциональных материалов». #российскиеученые #ионх

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Полиморфизм координационных пероксосоединений Учеными из Института общей и неорганической химии им. Н.С. Курнакова РАН и Факультета химии Высшей школы экономики получены и охарактеризованы два кристаллических полиморфа дикумилпероксида трифенилсурьмы(V) Ph3Sb(OOCMe2Ph)2. Это первый известный случай полиморфизма координационных пероксосоединений. Анализ кристаллических структур пероксокомплексов р-элементов показал, что комплексы с органическими пероксидами, пероксо- и гидропероксолигандами имеют схожие геометрические параметры координационного фрагмента Э-О-О, что может быть проявлением близких координирующих свойств различных типов пероксолигандов. Результаты работы, выполненной в рамках проекта РНФ (№ 24-13-00426), опубликованы в журнале Structural Chemistry. N.S. Mayorov, P.A. Egorov, A.G. Medvedev, A.A. Mikhaylov,E.V. Fatyushina, I.A. Buldashov, P.V. Prikhodchenko. Polymorphism of triphenylantimony(V) bis cumylperoxide. Structural Chemistry (2024). DOI: 10.1007/s11224-024-02434-x. https://doi.org/10.1007/s11224-024-02434-x #российскаянаука #ионх

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https://t.me/s/incredible_chemistry

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NEUTRAL

eng

NOT SPAM

Ну наконец-то! Открыли молекулу прием которой заменяет занятия спортом!

https://t.me/incredible_chemistry/375?embed=1&mode=tme

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https://t.me/s/incredible_chemistry

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POSITIVE

rus

NOT SPAM

«Поскольку лактат может выполнять роль глюкозы в мозге в стрессовых или травматических условиях, были проведены эксперименты по повышению уровня лактата у людей с сотрясением мозга. Пациенты, которые не могут выполнять интенсивные физические упражнения, получат большую пользу от препарата, который может повысить этот уровень», – объясняет Поулсен. Подробнее: Rasmus N. Ottosen et al, Preparation and Preclinical Characterization of a Simple Ester for Dual Exogenous Supply of Lactate and Beta-hydroxybutyrate, Journal of Agricultural and Food Chemistry (2024). DOI: 10.1021/acs.jafc.4c04849 Journal information: Journal of Agricultural and Food Chemistry

https://t.me/incredible_chemistry/377?embed=1&mode=tme

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https://t.me/s/incredible_chemistry

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ЩЕЛОЧНАЯ ФОСФАТАЗА. Низкие значения Итак, на прошлой неделе мы узнали с вами, что щелочная фосфатаза, важнейший фермент, который работает во всех органах и тканях, но особенно активен в печени и костной ткани, поставляя свободный фосфат на различные метаболические пути. Логично, что ее повышение - в первую очередь, маркер повреждения печени (особенно при желтухе) и костной ткани. 🤔 Но почему она может снижаться и какой диагностический смысл это несет? В целом, снижение ЩФ носит более доброкачественный характер, но тем не менее это может интерпретироваться, как маркер следующих проблем: 1️⃣ Дефицит цинка и магния Здесь все просто. Цинк и магний коферменты щелочной фосфатазы и формируют ее активный центр. Мало коферментов, мало и самих активных ферментов. 2️⃣ Избыток витамина Д Витамин Д при избытке стимулирует распад и резорбцию костной ткани, с целью повысить свободный Ca2+ в плазме крови, а потому активность щелочной фосфотазы, которая, наоборот, минерализует костный матрикс, будет уменьшаться. 3️⃣ Дефицит белка, недоедание, глютеновая болезнь, энтериты В целом тут все просто. Экзогенный белок - строительный материал для наших ферментов. Не хватает белка по какой-то причине, не хватает и ресурсов на анаболизм (строительство и синтез). 4️⃣ Дефицит витамина С. Витамин С - донор электронов для синтеза белка коллагена, который формирует в том числе и костную ткань. Если не хватает аскорбиновой кислоты, то и рост костной ткани замедляется. А потому и активность ЩФ снижается. 5️⃣ Гипофункция щитовидной железы. Точкой приложения гормонов щитовидной железы являются в том числе и остеобласты - клетки костной ткани, которые синтезируют коллаген и ответственный за синтез костной ткани. При снижении функции щитовидной железы, активность остеобластов тормозится, а потому и количество ЩФ уменьшается. Вот такие вот причины! Расскажите, а что еще вас интересует по этому ферменту? 😊

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NEUTRAL

rus

NOT SPAM

Откуда берется накипь в чайнике. Что нужно знать про жесткость воды Жёсткость — это важное свойство воды, которое зависит от содержания в ней растворенных солей кальция (Са2+) и магния (Mg2+). Эти элементы поступают в воду в результате процессов растворения и химического вымывания горных пород. Суммарное содержание в воде солей кальция и магния называют общей жесткостью. А она разделяется на временную и постоянную. Давай разбираться, в чем разница. Временная жёсткость связана с наличием в воде гидрокарбонатов кальция и магния. У этих соединений есть характерное свойство — при нагревании они осаждаются в виде нерастворимых карбонатов и удаляются из раствора. Это и есть накипь , которую мы наблюдаем в чайнике. Лайфхак: чтобы избавиться от нее, прокипяти воду с лимонной кислотой, она растворит твердый налёт. Постоянная жесткость связана с наличием других кальциевых и магниевых солей сильных кислот (сульфаты, хлориды, нитраты). Эти соединения остаются в растворенном виде даже после кипячения, поэтому такую жёсткость называют постоянной. Умеренно жесткая вода не опасна в гигиеническом отношении — с водой в организм поступает 20-30% кальция, который нужен для нормального обмена веществ. А вот высокая жесткость ухудшает органолептические свойства: вода выглядит мутной, можно разглядеть взвесь растворенных солей, появляется горьковатый привкус . Если заметили, что овощи развариваются хуже , а от моющих средств плохо образуется пена — это значит, что вода жесткая. В промышленности жесткость воды строго контролируется . Такая вода непригодна для питания паровых котлов и для охлаждения оборудования из-за образования плотных слоев накипи . А я уже вижу, как вы побежали проверять, хорошо ли намыливается губка от мыла 😂

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Как очищается водопроводная вода У каждого в доме есть водопровод 🚰 . Из него в наш дом поступает вода, которую мы очень часто используем не только для мытья посуды 🚿 , но и для утоления жажды. Однако большинство людей не знают как очищается водопроводная вода. Поэтому сегодня об этом. Сначала воду отбирают из рек, озер, водохранилищ или подземных резервуаров ⛲️ . Вся эта вода находится в заборе. После этого наступает механическая очистка воды. С помощью пропускания через крупную сетку из воды удаляют загрязнения большого размера 🕳 . Механическая очистка делает воду безопаснее для других систем водоподготовки. Следующий этап это добавление коагулянтов. Они способствуют слипанию дисперсных частиц, взвешенных в воде. В результате образуются частицы, от которых можно избавиться отстаиванием. При медленном перемешивании небольшие частицы слипаются. При достижении определенного размера они оседают на дно, и от них можно избавиться отстаиванием.Не опавшие на дно частицы, отделяют фильтрованием через слои углерода, песка 🏖 и гравия. Фильтрующий материал очищается током воды и прокачкой воздуха. 💧 Кислая вода может вызывать коррозию водопровода. Её пропускают через известковый фильтр до понижения кислотности. К воде с щелочной реакцией добавляют кислоты. Эта часть называется корректировка рН. Далее следует стадия осаждения. В ней вода обрабатывается ортофосфатами 🌧 , которые дают нерастворимые осадки с катионами кальция, магния и ряда тяжелых металлов, удаляя их из воды. Затем вода обрабатывается хлором, который убивает микроорганизмы и вирусы, что препятствует распространению болезней, передающихся с питьевой водой(холера, тиф). Хлор в воде из под крана остаётся для угнетения роста патогенов. Иногда вводят фторид-ионы для защиты от кариеса. После этого вода поступает из кранов в наш дом. 🚰

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[{"ner":"Хлор","lemma":"хлор","label":"PER","start_pos":1650,"end_pos":1654}]

NEUTRAL

rus

NOT SPAM

​​ О рафинированном масле 🌻 Мало кто знает, но наша страна является не только одним из лидеров по добыче нефти , но и крупнейшим производителем подсолнечного масла — на долю России приходится около 25% от всего мирового производства 🌏 В кулинарии у растительных масел особое применение — заправка салатов и жарка горячих блюд. Причём мы чётко понимаем, что нельзя жарить на масле прямого отжима, а добавлять рафинированное масло в греческий салат — бессмысленная затея . Но задумывались ли вы, в чем разница между рафинированными и нерафинированными маслами? Какие этапы проходит то самое «масло для жарки», прежде чем попасть на сковородку? Из сырья масло можно получить несколькими способами. Самое очевидное — это холодный отжим . Берём семена подсолнечника, очищаем от кожуры и под прессом выдавливаем масло, в котором сохраняются все полезные природные вещества. Более продвинутый вариант — горячее прессование . Чтобы более эффективно извлечь масло из семян, их предварительно обжаривают, при этом усиливается аромат, но часть натуральных компонентов утрачивается 🍳 И самое полное извлечение достигается наиболее распространённым и дешёвым методом — экстракцией . Сырьё после первичного прессования обрабатывается растворителями — бензином особой марки или гексаном. При этом масло из жмыха практически полностью переходит в органические растворители 🧪 Но не стоит переживать, что на полках в продуктовых магазинах нам продают бензин в бутылках. После экстракции растворители полностью удаляются путём вакуумной отгонки. Перечисленными способами получают нерафинированные масла, то есть такие, в которых в зависимости от исходного сырья сохранён запах, вкус, цвет и природные вещества. Их принято добавлять в готовые блюда для улучшения вкусовых качеств 🥗 Чтобы получить такое масло, которое сохранило лишь консистенцию и смазывающий эффект , его подвергают дальнейшим стадиям очистки 👀 На первом этапе проводят гидратацию — обработку небольшим количеством горячей (до 70 °С) воды. Содержащиеся в масле фосфолипиды при это выпадают в осадок, после чего отделяются на центрифугах. Эти вещества хоть и полезны, но не стабильны в масле. При длительном хранении они склонны выпадать в осадок, а при жарке на сковороде — гореть 🔥 На следующем этапе масло обрабатывают фосфорной кислотой и щелочью , чтобы нейтрализовать свободные жирные кислоты и отделить то, что не до конца ушло вместе с водой. Этот процесс по сути представляет собой омыление масла. Натриевые соли жирных кислот , образующиеся на данной стадии, являются основой хозяйственного мыла и напрямую продаются соответствующим компаниям-производителям бытовой химии 🧼 Третий этап — отбеливание . Масло пропускают через адсорбенты природного происхождения (специальные глины), которые поглощают красящие компоненты. Природная насыщенная окраска сменяется на бледно-жёлтую. После отбеливания масло вымораживают для удаления воска , которым покрыто большинство масличных культур 🕯 При охлаждении воск образует осадок, который удаляют с помощью фильтра, получая на выходе прозрачное масло. Завершающая стадия — дезодорация . В условиях вакуума масло обрабатывают струей горячего пара (230—240°С), при этом извлекаются последние пахучие вещества. 💨 И только пройдя все круги ада , растительное масло становится обезличенным — без цвета, вкуса и запаха . Но пригодным для жарки и приготовления продукции, где привкус растительного масла нежелателен, — майонез, маргарин и кондитерский жир 👩🏻‍🔬

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NEUTRAL

rus

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​​ Какую соль выбрать? 🧂 Соль — самая распространённая пищевая добавка, без которой не обходится ни одно блюдо в ресторане или на кухне 🥗 При этом, химический состав её предельно прост и знаком каждому. Откуда тогда на полках в магазине берётся такое разнообразие хлорида натрия? И почему стоимость одной упаковки может быть в десять раз больше, чем другой? Начнём с того, как добывают пищевую соль . ГОСТ выделяет четыре способа производства , которые указывают на упаковке: Каменная соль добывается в шахтах или карьерах из соляных залежей, не подвергаясь тепловой и водной обработке ⛏ Выварочную соль выпаривают из соляных растворов. Бывает так, что строить целую шахту для добычи соли невыгодно. Тогда бурят небольшие скважины, заливают их водой, которая растворяет соль, затем рассол выкачивают, фильтруют и вываривают 💨 Встречаются также естественные подземные рассолы, с которыми поступают аналогичным образом. Садочную соль осаждают из соленой воды в специальных бассейнах. В теплый сезон в местностях с подходящим климатом вода испаряется из искусственных плоских водоёмов, оставляя следы соли 🏝 И, наконец, самосадочная соль — это та, которая оседает естественным образом на дне водоема. Чаще всего это озерная соль. На самом известном в России соляном озере — Баскунчак — получают до 80 % от общей добычи соли в стране 🗻 Согласно одному из основных законов химии — закону постоянства состава — определенное химически чистое соединение, независимо от способа получения , состоит из одних и тех же химических элементов. Вне зависимости от того, как был получен хлорид натрия , он будет иметь однозначную формулу NaCl и обладать одинаковыми химическими свойствами 👁 Другая сторона вопроса — сорт соли , который определяет внешний вид, цвет, вкус, запах и состав продукта. ГОСТ выделяет четыре сорта , для каждого из которых указано минимальное содержание содержание чистого хлорида натрия: экстра — 99,7% , высший — 98,4% , первый — 97,7% , второй — 97% . Остальные проценты — это следование содержания других минералов , характерных для места добычи соли (кальций, магний, калий, железо и т.д.). Эти элементы необходимы для нормальной работы нашего организма, правда получаем мы их в основном из другой пищи 🍎 Как можно заметить, соль ЭКСТРА — это практически химически чистый реактив, подходящий для экспериментов в лаборатории 🧪 А соль первого и второго сорта может иметь тёмные вкрапления соединений железа и других минералов, которые никак не сказываются на её вкусовых качествах. И другая характеристика соли — это помол . Занятно, что при использовании крупной соли блюдо сложнее пересолить , потому что в щепотке крупного помола хлорида натрия на самом деле меньше, чем в щепотке мелкого из-за наличия пустот между кристалликами 💎 Вывод . Как бы ни старался современный маркетинг , вкус дорогой морской соли ничем не будет отличаться от дешёвой каменной. Чем ниже сорт, тем больше содержание других полезных элементов , а чем крупнее помол, тем лучше соль ведёт себя при готовке . И не стоит бояться тёмных частиц — это лишь вкрапления других минералов . Но обращайте внимание на состав 😉 Иногда в соль добавляют компоненты против слёживания и комкования . Если вы желаете купить натуральный продукт , выбирайте упаковку с наиболее кратким и лаконичным составом 👩🏻‍🔬

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https://t.me/s/ychemistry

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NEUTRAL

rus

NOT SPAM

Запускаем ракету на жидком азоте.

https://t.me/chemistrytg2021/9550?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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NEUTRAL

rus

NOT SPAM

Реакция протекает с выделением большого количества теплоты и с образованием пористого углерода черного цвета.

https://t.me/chemistrytg2021/9551?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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NEUTRAL

rus

NOT SPAM

Съедобный золотой лист из сусального золота.

https://t.me/chemistrytg2021/9552?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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NEUTRAL

rus

NOT SPAM

Полиакрилат натрия (C3H3NaO2) Этот супервпитывающий полимер способен поглощать воду в 100–1000 раз больше своей массы.

https://t.me/chemistrytg2021/9553?embed=1&mode=tme

https://t.me/

https://t.me/s/chemistrytg2021

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NEUTRAL

rus

SPAM

Eu/Tb люминесцентный термометр с исключительно высокой и стабильной чувствительностью в диапазоне 180 до 320 K Ученые из Московского государственного университета им. М.В. Ломоносова, Физического института им. П.Н. Лебедева РАН, Национального исследовательского университета «Высшая школа экономики», Института общей и неорганической химии им. Н.С. Курнакова РАН решили проблему реализации точных измерений температуры с помощью термометров на основе редкоземельных элементов, которые, как правило, характеризуются пониженной температурной чувствительностью и ограниченным рабочим диапазоном. В рамках исследования были синтезированы новые люминесцентные координационные соединения европия(III), гадолиния(III) и тербия(III) с фурансодержащим аналогом трифторацетона и показано, что смешанный металлокомплекс (Tb0.94Eu0.06) демонстрирует широкий и стабильный диапазон максимальной температурной чувствительности 3% × K-1 в области от 180 до 320 K. Результаты работы, опубликованные в журнале Sensors and Actuators: A. Physical, способствуют расширению теоретических и практических знаний в области синтеза и применения смешанных координационных соединений лантанидов, а также открывают новые возможности для разработки высокоэффективных лантанидных люминесцентных термометров с предсказуемыми характеристиками для использования в оптоэлектронных и микрофлюидных приложениях, криобиологии, для микроскопического обнаружения термогенеза в живых клетках, тепловизионной диагностики микроэлектронных компонентов и контактов интегральных схем. Anna A. Ivanova, Trofim A. Polikovskiy, Victoria E. Gontcharenko, Vladislav M. Korshunov, Mikhail A. Kiskin, Ilya V. Taydakov, Yury A. Belousov. Precision across temperatures: Eu/Tb luminescent thermometer with exceptionally high and stable sensitivity from 180 to 320 K. Sensors & Actuators: A. Physical. 2024. Vol. 379. P. 115969 https://www.sciencedirect.com/science/article/pii/S0924424724009634 #российскаянаука #ионх

https://t.me/chemrussia/5180?embed=1&mode=tme

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https://t.me/s/chemrussia

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Подведены итоги Конкурса молодежных научных работ имени выдающихся ученых ИОНХ РАН. В 2024 году конкурс проводился по трем номинациям. Поздравляем победителей! 1. Конкурс имени академика Н.М. Жаворонкова (за работы в области химической технологии и физико-химических основ процессов разделения и концентрирования) : - н.с., к.х.н. Лупачев Е.В.; н.с., к.х.н. Полковниченко А.В.; м.н.с. Кисель А.В. (ИОНХ РАН) «Разделение промышленных смесей структурных и пространственных изомеров перфторированных циклоалканов» 2. Конкурс имени академика И.В. Тананаева (за работы в области химии редких элементов, керамических материалов и наноматериалов) : - н.с., к.х.н. Веселова В.О. (ИОНХ РАН) «Методы получения высокодисперсного Bi4Ge3O12 для сцинтилляционных применений» - н.с., к.х.н. Юрова П.А.; н.с., к.х.н. Воропаева Д.Ю.; ст. лаб.-иссл. Манин А.Д. (ИОНХ РАН) «Ионообменные мембраны для альтернативной энергетики и электромембранных процессов» 3. Конкурс имени академика И.И. Черняева (за работы в области координационной химии и химии платиновых металлов) : - н.с., к.х.н. Ромашев Н.Ф., м.н.с. Бакаева И.В., ст. лаб. Комлягина В.И. (ИНХ СО РАН) «Координационные соединения платиновых металлов на основе редокс-активных аценафтениминов: перспективные противоопухолевые агенты» - н.с., к.х.н. Шмелев М.А., м.н.с. Чистяков А.С. (ИОНХ РАН) «Химическое конструирование фотоактивных смешанноанионных координационных соединений» #ионх

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[{"ner":"Почетного Химика","lemma":"почётный химик","label":"LOC","start_pos":120,"end_pos":136}]

POSITIVE

rus

NOT SPAM

https://telegra.ph/YAdovitye-knigi-s-toksichnymi-krasitelyami-08-23

https://t.me/incredible_chemistry/371?embed=1&mode=tme

https://t.me/

https://t.me/s/incredible_chemistry

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NEUTRAL

eng

NOT SPAM

https://telegra.ph/Kak-aromat-kormov-delaet-ih-vkusnee-dlya-sobak-08-27

https://t.me/incredible_chemistry/372?embed=1&mode=tme

https://t.me/

https://t.me/s/incredible_chemistry

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NEUTRAL

eng

NOT SPAM

https://telegra.ph/CHto-skryvaetsya-za-zlovoniem-duriana-09-02

https://t.me/incredible_chemistry/373?embed=1&mode=tme

https://t.me/

https://t.me/s/incredible_chemistry

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